Material selection can impact metal chemistry
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Figure 1: Differences in alloy segregation in steel test
castings based on breaker core size and shape:
A) 40% round sand breaker; B) 50% round sand
breaker; C) 70% round sand breaker; D) sand star
breaker. |
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Figure 2: Simulation Fraction Liquid results, B50 on
left compared to star contact on right at t=562 sec.
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Feeding aids like insulating or exothermic riser sleeves and hot-toppings can improve the overall quality and cost of steel castings. Their uses have been studied long and well, however these materials can impact the chemistry of the metal in the riser and potentially in the casting. This can occur by two mechanisms that have been studied extensively by ASK Chemicals.
The first mechanism is the feeding aid that intentionally slows the solidification of metal in the riser; this can lead to the segregation of certain alloying elements in the riser and potentially in the casting below the riser, causing under-riser cracking and other problems. The second mechanism is direct contamination into the riser or casting from the pickup of certain elements from the feeding aid materials.
Alloy segregation and under-riser cracking is usually only a problem when breaker cores are used to facilitate the removal of the riser. Earlier work showed that breakers with openings less than 70% of the riser diameter could cause segregation in the casting. However, new tests conducted by ASK Chemicals have shown that using different materials and geometries for the breaker core can minimize segregation while improving riser removal.
Aluminum pickup into the riser and casting from exothermic
feeding aids is a serious concern because of the potential to
produce aluminum nitride (AlN), which is known to embrittle
steel castings. Tests were conducted to quantify the amounts
of contamination from different types and formulations of
feeding aids. Test cube castings were produced with different
riser sleeve materials, and then the risers and castings were
sectioned and local chemistry was analyzed, and the following
conclusions were drawn:
Alloy segregation can occur under the riser if the size of
the opening, geometry and breaker core composition are not
controlled or designed for the casting being fed (see Fig. 1.)
The star breaker core design offers an improvement in
the break-off of the riser from the casting and an apparent
improvement in the feeding of the casting without alloy segregation
compared to standard round breaker cores of the same
cross-sectional area.
The sand breaker cores are not as thermally transparent as
previously believed. The size of the sand breaker core opening
will affect its overall performance, which is dependent upon
the chemistry of the metal and the geometry of the casting.
Exothermic breaker cores can offer improved feeding
through a smaller opening as compared to a sand breaker core.
They can result in easier riser break-off and cleaning of the
casting.
Mathematical calculations show that a star breaker core
design will be about 21.5% easier to break-off than a round
breaker core where both cross-sectional areas are the same.
Modeling can be an effective tool for determining the performance of your riser and breaker core design even before the
first casting is made.
Hot topping materials showed varying results. The degree
of contamination depends on the formulation of the hot topping
material.
reviewed the effects of the breaker cores and their overall performance in feeding a casting, from the size of its opening, to the materials it is made from, and to the shape of its contact area (see Fig. 2 on the comparison of fraction liquid between a 50% round sand breaker core and a similar sized sand star breaker core.) This provides evidence that the star breaker core design can improve the thermal profile at the contact area and reduce alloy segregation as the casting solidifies.
ASK Chemicals’ riser sleeves and auxiliary products are
based on patented technology, employing a fiber-free refractory
base bonded with ASK Chemical’s cold box resins. This
design offers several advantages over the traditional fiber-based
riser sleeves, including excellent dimensional accuracy, high-strength, low gas evolution, and uniform chemical compassion.
Riser sleeves are available in a variety of formulations:
IN Series The IN series is an insulating formula designed
for use with all metals including steel up to 4 inch section
thickness
STL Series The STL series is a high-grade insulating formula
designed for use with heavier sectioned steel castings 3.5
inches thick and above
EX Series The EX series is a standard grade exothermic
formulation designed for use with all ferrous metals
EXF The EXF series is a high-performance, fast igniting,
fluorine-free, exothermic formulation that was developed for
ductile iron to eliminate fish-eye defects associated with the
green sand contamination by traditional fluoride-containing
exothermic riser sleeves. The low energy required to ignite
these sleeves makes them very effective in cold riser applications.
They also can be used in steel applications where fast
ignition is required.
ASK Chemicals also offers EXACTCAST Floating Cover Lids that can improve the consistency of a riser’s feeding efficiency dramatically while also addressing safety concerns. Many of the foundry variables are eliminated when FCL’s are used, such as: how much hot topping was used, when was it applied and did it really cover the riser evenly. Tests in both the lab and in the foundry confirm the overall performance and consistency improvements when EXACTCAST Floating Cover Lids are used compared to the use of traditional hot topping materials.
The EXACTCAST riser sleeve technology also offers opportunities foe foundries to design a gating and feeding system for their castings. Instead of having to use standard shapes, foundries can work with ASK Chemicals’ technical representatives to design custom shapes that will help to maximize feeding efficiency and further lower casting costs.
Lee Horvath is the global product manager for ASK Chemical Feeding Aid product line. Visit www.ask-chemicals.com for more information.


